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Sandbox Physics

Big Bang Nucleosynthesis: Light Elements in the First Minutes

How do temperature and expansion speed decide today’s helium and deuterium? Expansion sets the clock and temperature sets the gate. Neutrons stop turning into protons about one second after the big bang, then decay until the universe is cool enough, three to four minutes later, for deuterium to survive. Almost every neutron left at that moment ends up in helium. Denser baryons burn more deuterium away, and faster expansion leaves more neutrons and more helium.

Drag the cosmic clock through the first hours and watch free neutrons decay, wait, then lock into helium. Change the baryon density and the extra radiation to see the final helium, deuterium and lithium move.

Interactive modelBig Bang Nucleosynthesis: Light Elements in the First Minutes
Helium-4 mass fraction YpY_p0.2420.242
Deuterium per hydrogen D/H\mathrm{D/H}2.56×10−52.56\times10^{-5}
Lithium-7 per hydrogen 7Li/H{}^{7}\mathrm{Li/H}4.49×10−104.49\times10^{-10}
Neutrons per proton at 109 K10^{9}\,\mathrm{K}0.1530.153

What the first hours leave behind

Neutrons nnProtons ppDeuterium D\mathrm{D}3He+3H{}^{3}\mathrm{He}+{}^{3}\mathrm{H}Helium-4 4He{}^{4}\mathrm{He}7Li+7Be{}^{7}\mathrm{Li}+{}^{7}\mathrm{Be}
Mass fractions through time

Model calculation

Neutrons drop at once when helium forms.

Final abundances against baryon density

Model curves; grey bands observed (PDG 2025); green band from the microwave background

Lithium-7 comes out about three times above stars.

Which nuclear rates move the result

Model; each rate moved by its one-sigma error (Serpico 2004)

d(p,γ)3He\mathrm{d}(p,\gamma){}^{3}\mathrm{He} sets most of the deuterium error.

Follow the neutrons from one second to three minutes

BackgroundA second after the big bang the universe is a hot soup of photons, electrons, positrons, neutrinos and a thin sprinkling of neutrons and protons. Weak reactions turn neutrons and protons into each other, and photons break apart any deuteron that forms.

Why it mattersAlmost all of today’s helium and deuterium was made in these few minutes, so their abundances record how hot the universe was, how fast it expanded and how many baryons it held.

Focus question
Why does nearly a quarter of the ordinary mass end up as helium, and why is a little deuterium left over?
One-sentence intuition
Helium counts the neutrons that survive until deuterium can hold together. Expansion sets that waiting time, so more radiation means more helium. Deuterium is the leftover fuel: more baryons burn it further, which is why D/H\mathrm{D/H} measures the baryon density.

Core mathematical model

Neutrons and protons stop trading

np∣eq=exp⁡ ⁣(−QkBT),Q=(mn−mp)c2=1.293 MeV\left.\frac{n}{p}\right|_{\mathrm{eq}}=\exp\!\left(-\frac{Q}{k_BT}\right),\qquad Q=(m_n-m_p)c^2=1.293\,\mathrm{MeV}

While weak reactions are fast, the ratio follows the temperature. Near kBT≈0.7 MeVk_BT\approx0.7\,\mathrm{MeV} they become slower than the expansion. The ratio stops following the temperature at about one neutron for every five protons, then falls slowly because free neutrons decay with lifetime τn≈879 s\tau_n\approx879\,\mathrm{s}.

Expansion rate from the radiation

H2=8πG3 π230 g∗(kBT)4(ℏc)3c2,g∗=2+78[4+2(3+ΔNeff)(TνT)4]H^2=\frac{8\pi G}{3}\,\frac{\pi^2}{30}\,g_*\frac{(k_BT)^4}{(\hbar c)^3c^2},\qquad g_*=2+\frac{7}{8}\left[4+2\left(3+\Delta N_{\mathrm{eff}}\right)\left(\frac{T_\nu}{T}\right)^{4}\right]

Before electron-positron pairs annihilate, photons, pairs and neutrinos fill the energy density. Each extra neutrino-like species ΔNeff=1\Delta N_{\mathrm{eff}}=1 raises the expansion rate, so weak reactions freeze earlier, fewer neutrons decay, and more helium forms. In this model the helium fraction rises by about 0.013 per extra species.

Why deuterium waits

XdXnXp∝η(kBTmNc2)3/2exp⁡ ⁣(BdkBT),Bd=2.224 MeV\frac{X_d}{X_nX_p}\propto\eta\left(\frac{k_BT}{m_Nc^2}\right)^{3/2}\exp\!\left(\frac{B_d}{k_BT}\right),\qquad B_d=2.224\,\mathrm{MeV}

There are more than a billion photons for every baryon, so even when kBTk_BT is far below the deuteron binding energy, the rare energetic photons still break deuterons apart. The small factor η\eta delays deuterium until about kBT≈0.07 MeVk_BT\approx0.07\,\mathrm{MeV}, a few minutes after the big bang. Only then can the chain to helium start.

Helium counts the surviving neutrons

Yp≈2 (n/p)1+n/pY_p\approx\frac{2\,(n/p)}{1+n/p}

Nearly every neutron still free when the bottleneck opens ends up in helium-4, which holds two neutrons and two protons. With n/p≈1/7n/p\approx1/7 this gives Yp≈0.25Y_p\approx0.25. The full network in this Lab gives 0.242 for three neutrino species, which corresponds to n/p≈0.138n/p\approx0.138 when the bottleneck opens.

Common difficulties

Cooling below the binding energy is not enough

Typical misconceptionDeuterium forms as soon as the temperature drops below its binding energy of 2.2 MeV.

Better mental modelPhotons outnumber baryons by more than a billion to one. The high-energy tail of the photon distribution keeps breaking deuterons until the temperature is about thirty times lower.

More baryons do not mean more deuterium

Typical misconceptionA denser universe should make more of every element.

Better mental modelHelium rises only slightly with density, while deuterium falls steeply because denser matter burns it into helium-3 and helium-4 faster. The sparse-baryon preset leaves about six times more deuterium than our universe.

The lithium curve is a prediction, not a fit

Typical misconceptionThe model is tuned so that every element matches observation.

Better mental modelOnly the baryon density and the radiation are inputs, and they are fixed independently by the cosmic microwave background. With them, helium and deuterium agree with observation, but lithium-7 comes out about three times higher than in old halo stars. That gap is still unexplained.

Run the experiment

  1. 01

    Watch one run of the first hours

    Let Our universe play from the start, then drag along the cosmic clock to about 200 seconds.

    What to observe: Blue neutrons fade slowly at first. Around three to four minutes they pair with protons and the box fills with gold helium nuclei in a few tens of seconds.
  2. 02

    Change the baryon density

    Compare Sparse baryons keep deuterium with Dense baryons burn deuterium, then drag the baryon slider slowly between them.

    What to observe: D/H\mathrm{D/H} drops by a factor of about thirty from the first to the second, while the helium fraction only moves from 0.230 to 0.250. The observed deuterium band meets the curve just beside the green microwave-background band.
  3. 03

    Speed up and slow down the expansion

    Compare Extra radiation, more helium with Slower expansion, less helium.

    What to observe: The neutron-to-proton ratio at 109 K10^{9}\,\mathrm{K} moves from 0.143 to 0.165 and the helium fraction from 0.228 to 0.261. One extra species shifts helium by about four times the observed one-sigma error, so only a small change in radiation is allowed.
  4. 04

    Find the rates that matter

    Return to Our universe and read the chart of nuclear rates below the scene.

    What to observe: Moving d(p,γ)3He\mathrm{d}(p,\gamma){}^{3}\mathrm{He} by its published error changes deuterium by about 0.7 percent, and lithium-7 responds most to that rate and to 3He(α,γ)7Be{}^{3}\mathrm{He}(\alpha,\gamma){}^{7}\mathrm{Be}. These errors are far too small to close the lithium gap.

Related experiments and articles

What this page links to directly

The first minutes and the light elements · Reading path

From the first second to the light elements

Articles on this path that use this experiment, followed by the other experiments they suggest.

  1. ArticleHow temperature and expansion speed set helium and deuterium
  2. ArticleWhen neutrons and protons stop turning into each other
  3. ArticleWhy deuterium waits for the universe to cool
  4. ArticleHow baryon density and extra radiation move the light elements
  5. ArticleRecompute a small network from a frozen rate grid and propagate rate errors
  6. ArticleReading the BBN evidence on extra radiation and the lithium problem
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