Magnetization precesses about the field
Point the static field along and call it . The sum of all proton magnetic moments in a unit volume is the magnetization , in A/m. A proton’s magnetic moment points along its spin angular momentum, and the ratio between them is the gyromagnetic ratio .
The field exerts a torque on the magnetization, the torque changes the angular momentum, and the result is Eq. 11 of Bloch’s paper. The cross product is always perpendicular to , so the magnetization keeps its length and only swings round . That swinging is precession, and its angular frequency is the Larmor frequency.
For the proton ; the MIT handout rounds this to 42.58 MHz/T. The frequency is proportional to the field, and Chapter 3 turns that proportionality into an image.
Source: F. Bloch · J. Hrabe · MIT 6.3000 Signal Processing
A radio-frequency pulse tips the magnetization over
At equilibrium the magnetization lies along , parallel to the field. It does not precess, and a coil cannot detect it. To make it precess we first push it off the axis with a weak perpendicular field that rotates at : a radio-frequency pulse.
Seen from a frame that turns about at , the rotation cancels the static field and stands still. The magnetization then turns slowly about alone, at . Bloch makes exactly this change of variables in his Eqs. 40–42, which turns the equations into a system with nearly constant coefficients.
After a pulse of length the magnetization has turned through the flip angle. After 90° it lies entirely in the transverse plane and, in the laboratory frame, precesses at . Its changing flux induces a voltage in the receive coil. The MIT handout calls this voltage the signal from which an MR image is derived.
Source: F. Bloch · MIT 6.3000 Signal Processing
Two relaxations: T1 and T2
Tipped magnetization does not precess forever. Bloch describes its return with the two simplest exponential laws. The longitudinal part returns to its equilibrium value with time constant (Eq. 32); for that the spins must hand energy to the surrounding molecules. The transverse parts and decay with (Eq. 37); for that the protons only need to fall out of step with one another, and no energy changes hands.
Bloch lumps the causes of this loss of step into an effective field irregularity and gets (Eq. 33). For neighbouring nuclei held still he estimates of about 1 gauss and of about . He notes that can be many orders of magnitude shorter than and that assuming the two equal can be a serious error.
Adding both relaxations to the torque gives Bloch’s Eqs. 38a–c, now called the Bloch equations. Below are their solutions in the static field alone.
Source: F. Bloch · MIT 6.3000 Signal Processing
Checking the equations by numerical integration
The closed-form solutions can be checked against direct integration. The benchmark program behind the frequency-encoding experiment integrates the Bloch equations with a fourth-order Runge–Kutta method. After a resonant rectangular pulse the computed flip angle differs from by less than ; without a pulse the magnetization turns in the sense given above; and the transverse part decays as the exponential solution says.
The program also splits each water tube into 400 small pieces, integrates each one and adds their contributions in the coil. The voltage obtained this way agrees with the Fourier formula of Chapter 3 to better than one part in a thousand, which is why the later chapters may use the formula instead of integrating point by point.
Worked example: one excitation in a 3 T scanner
Problem: in a scanner a 1 ms rectangular radio-frequency pulse tips the magnetization by 90°. Find the precession frequency, the required, the decay of the signal and the recovery of the magnetization. Take (the default of the frequency-encoding experiment) and ; both are assumed only for the calculation.
The precession frequency is : one turn takes 7.83 ns, and in 1 ms the magnetization turns 127,728 times. A flip of needs , about two millionths of . So weak a field works because it turns in step with the precession and its effect builds up turn after turn.
After the pulse the envelope of the coil voltage decays as and is down to after 30 ms. Meanwhile the longitudinal magnetization recovers from zero. If the excitation is repeated every 2 s, just before the next pulse, so in the steady state each excitation gives about 86.5 % of the fully recovered signal.
Source: J. Hrabe · MIT 6.3000 Signal Processing